Which method is used for COD?
Which method is used for COD?
The traditional chemical oxygen demand (COD) analysis method is the wet chemistry method. This involves a two hour digestion at high heat under acidic conditions in which potassium dichromate acts as the oxidant for any organic material present in a water sample.
How is COD measured in a lab?
COD is measured via a laboratory assay in which a sample is incubated with a strong chemical oxidant for a specified time interval and at constant temperature (usually 2 h at 150°C). The most commonly used oxidant is potassium dichromate, which is used in combination with boiling sulphuric acid.
How does a COD test work?
The COD test uses a chemical (potassium dichromate in a 50% sulfuric acid solution) that “oxidizes” both organic (predominate) and inorganic substances in a wastewater sample, which results in a higher COD concentration than BOD concentration for the same wastewater sample since only organic compounds are consumed …
Why potassium dichromate is used in COD?
Currently, most COD tests use potassium dichromate as the oxidant. Potassium dichromate is a hexavalent chromium salt that is bright orange in color and is a very strong oxidant. Between 95-100% of organic material can be oxidized by dichromate.
Why sulphuric acid is used in COD?
Chemical Oxygen Demand (COD) 1% Silver Sulphate in Sulphuric Acid (conc.) provides the primary and secondary digestion catalysts for oxidation of carbon during chemical oxidation.
How is chemical oxygen demand measured?
The most common test method is the colorimetric analysis after oxidizing the COD with acid and using indicator compounds, such as hexavalent dichromate. In some instances, however, there are compounds that will interfere with the colorimetric analysis, and titration is required to determine COD levels.
Why mercury sulphate is used in COD?
The most general COD determination uses potassium dichromate (K2Cr2O7) in excess in an acidic medium with the aid of silver sulfate (Ag2SO4) as a catalyst, and mercuric sulfate (HgSO4) added to remove interference of chlorides.
What is the ratio of BOD and COD?
In domestic waste the ratio between BOD/COD is 1:2. The COD/BOD ratio is useful for assessing the amount of sewage available for biological treatment.
What is COD and TSS?
Chemical oxygen demand (COD) is the amount of oxygen required to oxidize organic compounds (>500 milligrams per liter). Total suspended solids (TSS) is the total amount of suspended materials (>250 milligrams per liter).
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